h�bbd``b`aӁS���_@��8 We use cookies to help provide and enhance our service and tailor content and ads. �8y$�E��m����ؕ��x��ڟ;v��-�u~Q`��y�S�5� j��u�i/��������?�g�l��zw����T�?���6厼-?��fS�����Ŧ�}4���^��7��_n|;��lW��f�)��ևN��4��j����. '���w�9���$��V������T�M�-�>|8<>��a1�Mc�6l�f4)�4W�(Vql����{�U�!�q-��W�"�T����L�(�NF^\�2��ZFV����E'/�O����G��K�9�H7{�Z�$���Ċ=.d�E�� {�(t���s$d���LȓQ��=H'�2we��JZQ�A��3�7IM��l�أK�dlǭ�2畝4�d��+l��W��[�qMd��9�� k7�� �{b���9����h�~�X+�K��XᄖR���Hm �8j@V f"�O�ɯ �xm����\g��-� Advances in Colloid and Interface Science, https://doi.org/10.1016/j.cis.2014.10.010. We apply the model to the determination of the cmc from the pyrene fluorescence intensity, especially from the intensity ratio at two vibronic bands in the monomer emission or from the ratio of excimer to monomer emission intensity. H��WMo�6��W�HĈ�>�b��u���6��Cڃ�ȉZGl'i�}烤h! �'���R5��V��Dw���C�Wr. �1;z�a�q*s���`�:�U� ��k���!�v��3����gs�"Wj��ģ6`��cB�����A�z�X7��1r%�'~���l�hw�8zO\ƞ7"�q�=���q�O�x�p�C������4�~����P?����Ƚ)�b��_��C%��p�y�:��V��[֥ ��j�_�|E��o��[ ��}7��x��_�(���b/�/��Mq���'��8j�GN�4�������&*�K��1��wj�$ZW�>�$r�$����W��~���I���=1s�0s?�8�J�-�u���5�����oy����l���zU�W�r�f�f��;y�m�պ��*��3����r8�}�m{|ڭ�r�l���7yY�Ou���]��~�i��� .>����OQe���)7�նZk0�/�w�l��YQߟm�U�^۳UScfo��j�]����,����$^ ���;���� &25���#&��k�N��� ÿ1A7�� ��'6��)�ݷ����'l���t���� -̼ �-����� 1�"f獘�\21\��:o���7�vj*��f��Ɓ ����� �g �v ��D1��W�Q�jz5�� ��F ~��4!��!���"|��ٗ!�����0�ѽ;� �խ��@� �D:��`:z�U�ۑ�� ��6��h�B�+m%���e�+B�oC��[_��S�>U�K/���_m ?��A놛���_=�Ɓ��;��L\�6�� t^�����=W���������e�VU~���y��B��2�Nx���b u�:u#o|�������T�z���w�������ZB)̯���Ëm��JE(�]��9W�FG7�9ڹ� ��D`ws�-:�D�'� Kc? endstream endobj 807 0 obj <>stream endstream endobj startxref �Cd�>��yR�PEQ�n- %PDF-1.5 %���� _�L�1|�t8�����EA�C�~(hC�������g��iF���p+A�S���j7���6� H��VMo�8��W�H. 2�W���]�=)^; �8e3�S����$HE�zt5:9C5N�P�a�u����JY�F9���w�ڶݿ-~�(j_�7��CJ����Q:(bG�&� �6MԎ~ ���˃����El3Z�A'*���м.����&��b�4,_�!��s�C���_��9�����c4�s�/�t������S�LH�S��rے���FFFTuS��R'��X�JO�A����X���E��s|'M0^4d��%KsMtC��L��rK�i�w � `�YI�p��M��w� )�N���2?gg�zk�R�j���2��'̚����WeZ֕��Ě����_>�����Ç�_>�y�r����x��xV��q���UZ��K��;���2IØJ=��꧎!�P-��y��������:]W�-��ti���ҷ�ԃIr����#��&� �RߙJw<9m{�٘��� ScienceDirect ® is a registered trademark of Elsevier B.V. ScienceDirect ® is a registered trademark of Elsevier B.V. Fluorescence emission of pyrene in surfactant solutions. 883 0 obj <>stream H��VI��6�ϯ��*���[N-z���#�c��b�3�߷P��L�b?�o�������hc��ja�ϼ��D�ic�H�v&��a!�x�]%���Lnw�g��*��+�{�KQ#�?�uQ�5�]�!~��l)ת�B�]�m�6ob!O���w���u��4�bGV�9ҫ���ǒw��> |��(��39�VN�oA���b(K�F��NF�l5'D��Il�~���ߋVI)E���Y�+��u���� C�3�rQ��xAho�Qd����_���SU9>�G8���������r��8"*3�NEV]@��z�� #贬��e�"De.�9H�ߖ%I�-���'����:nZ�`�Q�J�ىy8w��vyMؙ�,�Pj�N�@n{֙��Y�e� H�a��;HZ��A;��wTZ��N1o���ˮ��0+*$1k��?.�̍�1��nZ�KS�����F4�`��8TgoB��,T?EjK�`� �PP�f ��U[��s�AM�)���T]�sڍKn]��H��v��!�S�v�0� �m?���a2�F�k��uY�[+�|��5�O��O 2), r = III/I, is a measure of the local polarity. |�ࡺ�hO?�͞{�.=��T�V$�5V��j��Թ��. We relate the finite width of the transition region below and above the cmc with the observed changes in the pyrene fluorescence in this region. The ratio of the intensities between the third and the first vibronic components of the pyrene emission spectrum (bands I at 373 nm and III at 385 nm) (Fig. 821 0 obj <>/Filter/FlateDecode/ID[]/Index[803 81]/Info 802 0 R/Length 91/Prev 1516617/Root 804 0 R/Size 884/Type/XRef/W[1 2 1]>>stream "> � B D���@�����`�.뀄#�F�M �G ���� �� ?�s*�N�c>w��ZQ��\d� ��^Z�L ϸ�u!Qk��%Wd��b2 ^yŪ�zz/9��= �GG�ZGG��� �L� �!D�ut40��� �@ J � ĸLD���@, `�gQޠ���зP�ѫ��.N���o�O\�p��m}�L,�,d�z� #X0�3��SҌ��� ��)i6�#`q� �� .�U�` |6~a v��b g�N�Ѹ,t��}7z���ȶ��h�e?і���/!�D��X#�����!������a�ϐn�ÞPPV� GZԀ��z�m"Nt�F6j��1%aj���������؞�Mm� Copyright © 2020 Elsevier B.V. or its licensors or contributors. endstream endobj 809 0 obj <>stream _�(,���P����C���g���Vb�v%߮�\���P�����du�!0hj��̟��'rm�9��rA�PK"�Z)��Di�!�Y���w�i�u.a�-�bB� �Ң�$Ls�$aFA� �� �9���3���BDI ��KF�R.8��Bw)�m$�N��"�Z��Dpz�!B�/�Bh�%\�gE�����48j������DKԬ1ʁg���QZ.00� The fluorescence emission spectrum of Pyrene dissolved in cyclohexane. =�T�݂wPOO��h�r�n'�n|(��x�6!wD�7x�x�Y}I����U(��J��`����mxM�ͨ� {j��� V�����9�oC�|;\`�VG1�sTa/K[�L��0��J�`l\���{��_��`�p!��Ă8'p6x�sh����X���^�Y�*Z��tp�B,�5��-f%W>+�Z�Z�ڄچ�u5dEW�P�P"����D�'�?���O2�����d�'����_�Ձ��5|����?����ޗ���/^�����?��r��2!2����3�+*Å�:��.�~��EWo��_�ӗuݴ/^ta5]V��2�bX�3�����N�˭�4�ƃ�e��Q��Ӫ��ؖuKج~��u�58�Q Ԥ>+B�(B�2Ir�)X� 8��H5� f5�e��&j��4�Y �D Z��,D�QC�h�A�j��4@P x�! �Vj��#��w��OG�7��Y����hn*~�4>���&y������@�q�{L�2� �:�� ��E�����3: �DCC[3gDl���D=��9]?�3�1�tj� D�L` ��,6>��f=�9 h��4���>2��ϸ��h�…����Ȫ�{�\Hޒ����)��+���w�����t'�)�r��LflL�8\�xv�&D���X�#�ϗ�H]������V*uH����{ڸ�k�sq�_ J^Ÿ �=� '�w;�~5v����k�x��-o/�4��o���>�/�.�/�qa�}���������)G#Y"cQ_j�3;P��4��M �+�kؘ�'�o:�����)W���W�7~�}L�K`M�׏Ϻ �F�F����8������7������SM��K諸��}��]c�������"o�0�_I�$�F���ݮ�ӗ;7��e��Fx�^�?�U�a��Z����IՃ���޽�!������:ș���CO��� cO|��OL�{�ɈB���t��:=-~������Fc�N��V�zؘ��c� ���Ռ��a�5F���h����p� 6��@=Zge7l�����A>F`ud�`�����p�AĮgc3�%¸B"��/����6��L%6uY��Jo��]��n���1��D�s�G��� ��H�yۆ?Îfe�A`扉�x���oODaO�Bw=>� ��x�N��x This spectrum was collected by in the summer of 1995 using a Spex FluoroMax. , is a fluorescent probe whose spectrum is sensitive to the polarity of its environment the quantum of., is a fluorescent probe whose spectrum is sensitive to the polarity of its environment excitation and emission monochromators set. 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